Solvent Effects, Solubility and Marcus Theory Application for the Solvatochromism of Re(II) Diimine Cyanide Complexes - Effect of Temperature on the Aquation of Tris (Ferrozine) Fe (II) Complex

Solvent Effects, Solubility and Marcus Theory Application for the Solvatochromism of Re(II) Diimine Cyanide Complexes - Effect of Temperature on the Aquation of Tris (Ferrozine) Fe (II) Complex

Lamees Zuhair Majjad Preferential solvation of Fe(phen)2(CN)2 and [Fe(phen)(CN)4]-2 were investigated in aqueous, dimethylformamide, 2-butoxyethanol, polyethyl-eneglycol 400, polyethyleneglycol 200 and n-propanol binary mixtures. The thermodynamic model of Frankel was used to treat preferential solvation in the binary aqueous organic mixtures and reveals that preferential solvation by the organic solvents occurs. Besides preferential solvation, Marcus theory and transfer chemical potential (solubility data) studies were made. Also the Arrhenius parameters for the aquation of tris (ferrozine) iron (II) were investigated under various aqueous organic mixtures. Lamees Zuhair Majjad Supervisor Prof. Bassem F. Shraydeh 199  Zajel / An-Najah National University